How To Take DVD Screen Shots In OS X
Screen shots are easy to do on the Mac using Apple’s Grab utility.
Unfortunately, Grab is disabled when watching a DVD with Apple’s DVD Player application. That makes it hard to use if you want to save an screen shot image of a DVD for say, a movie review or something.
Some programs you can use to take screen shots InstantShot! (suggested by reader Dave), VLC, and Handbrake in conjunction with Grab.
Use InstantShot To Take A Screen Shot
InstantShot! is like Grab on steroids. Launching InstantShot puts a little scissors icon in your menu bar. To take a screen shot, click on it and go to Shoot Screen > To Jpeg File. The screen shot appears in your user folder.

InstantShot has many other options for screen shots (within a rectangle, a timer, customizable keyboard shortcuts, file formats) which deserve a separate post.
Use VLC To Take A Screen Shot
VLC can play back DVDs. Insert a DVD into your computer drive and launch VLC. Go to File > Open Disc. A dialog box pops up that defaults to your optical disc drive.

You can then navigate through your DVD just like Apple’s DVD Player, and using the VLC controls. Start playing a scene until you find an image you want to capture.
Go to Video > Snapshot. VLC will export a captured image in PNG format.

Use Handbrake To Take A Screen Shot
This method is a “kludge” but works okay. Insert the DVD into your Mac’s optical drive and launch Handbrake. Click the “Picture Settings” button.

You’ll then see a section that shows a sample image from the DVD chapter you chose. Click the “Next” button to see some other representative images.

Then use Apple’s Grab utility to capture a screen shot from what’s displayed in Handbrake.
I said “kludge” because using Handbrake, you don’t have as much control over the images shown, and have to use Grab, but in a pinch it will suffice.
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May I suggest the excellent freeware app InstantShot? It’s one of my favorite Mac apps (better than Apple’s screengrab) and I use it daily as I have to grab a lot of screencaps and images for my website.
I think you’ll find it much simpler to use than the above approach…
Here’s the link:
http://projects.digitalwaters.net/index.php?q=i…
(it provides a number of ways to grab shots, there’s even a nice feature to set a timer and define a region so as you watch a show it will just grab shots every 10 seconds — or whatever interval you define. You can also have it sit up at the top of the desktop so you can always access it via the menubar)
Thanks for recommending that program. I just updated the post above. I ought to write a post on just InstantShot alone.